Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The 40Ar/39Ar geochronological technique has significantly contributed to the study of crustal deformation. However, the frequent occurrence of extraneous argon in high-pressure terrains can make the interpretation of 40Ar/39Ar ages problematic. This contribution attempts to: i) characterize the distribution and origin of extraneous argon in the Cycladic Blueschist Unit (CBU, Greece) by applying the 40Ar/39Ar dating technique on three Cycladic islands, Syros, Tinos and Ios, which span a complete transect of the CBU and ii) discuss regional implications for the tectonometamorphic evolution of the CBU. Our results, combined with ages available in the literature, show that periods of peak-burial conditions (55–49 Ma) and syn- (45–38 Ma) to post-orogenic exhumation (37–21 Ma) are well constrained in the CBU by the 40Ar/39Ar method. Moreover, Variscan apparent ages are preserved in the Cycladic basement of Ios, indicating that the 40Ar/39Ar system was not completely reset during the Eocene metamorphic episode. Additionally, our 40Ar/39Ar data show that the occurrence of extraneous argon is heterogeneously distributed in the CBU. While high-pressure rocks of Syros and Tinos are only locally affected, extraneous argon is clearly evidenced in the CBU of Ios, yielding geologically meaningless ages up to 900 Ma. On each island, the most affected ages were obtained in microstructures where fluid circulation is enhanced such as shear bands or strain shadows around garnets. We suggest that the Cycladic Basement, a polymetamorphic continental unit, behaved as an argon reservoir that has been mobilized by fluid circulation at the Eocene. These argon-enriched fluids have then heterogeneously contaminated metamorphic rocks when percolating through the CBU. Finally, we claim that a minimum closure temperature of 550 °C must be accepted for the phengites of the CBU and conclude that volume diffusion is not the main process resetting the argon isotopic system in high-pressure rocks compare to recrystallization enhanced by fluid circulation and deformation.
ISSN: 0024-4937

Droits : http://creativecommons.org/licenses/by-nc-nd/
insu-01424268
https://hal-insu.archives-ouvertes.fr/insu-01424268
https://hal-insu.archives-ouvertes.fr/insu-01424268/document
https://hal-insu.archives-ouvertes.fr/insu-01424268/file/Valentin-Lithos-Accepted-2016.pdf
DOI : 10.1016/j.lithos.2016.12.013

Éditeur(s) : HAL CCSD
Résumé : Geothermal energy is considered as a green and infinite energy source at human scale. Currently, the yield of geothermal power plants is limited to temperatures of the operating fluid which 350 °C. From tectonic and volcanic activity at mid-ocean ridges, Iceland is a location where supercritical fluid extraction (T> 375 °C) can considered for the near future. Exploiting such fluids could theoretically multiply by a factor of ten the electrical power delivered by geothermal wells. Can such fluids circulate at the base of brittle oceanic crust? This work investigates the petrophysical properties of basalts in order to constrain geophysical observations in Iceland and predict the behavior of very high temperature geo-hydrothermal reservoirs. The first approach consisted in studying the physical properties of rocks that have hosted deep hydrothermal circulations at oceanic ridges. The study of these rocks at ODP Site 1256 shows that the porosity measured both in the field and in the lab is associated with amphibolite facies alteration minerals (T> 500 ° C). The second approach was to recreate in the laboratory the conditions of pressure, temperature and pore fluid pressure of high temperature to supercritical hydrothermal systems to predict the mechanical and electrical properties of basalts under these conditions. The mechanical results indicate that the brittle/ductile transition occurs at a temperature of about 550° C, where a strong permeability decrease is expected. The implementation and calibration of a new cell for measuring electrical conductivity at high temperature provide the first results for the interpretation of geophysical data. When applied to basaltic crustal conditions in Iceland, these results indicate that hydrothermal fluids could circulate, at least temporarily, in a supercritical state up to 5 km depth.
La géothermie est considérée comme une source d'énergie propre et inépuisable à échelle humaine. Actuellement, le rendement des centrales géothermiques est limité à l'exploitation de fluides de températures inférieures à 350 °C. L'association de l'activité tectonique et volcanique aux dorsales océaniques fait de l'Islande un lieu où l'extraction de fluides supercritiques (T> 375 °C) peut être envisagée. Cette exploitation pourrait multiplier par dix la puissance électrique délivrée par le système géothermal. Ces fluides peuvent-ils circuler dans la croûte océanique ? Ce travail propose de contraindre les observations géophysiques et de prédire le fonctionnement des réservoirs géo-hydrothermaux de très haute température par l'étude des propriétés physiques des basaltes. La première approche est focalisée sur l'étude de roches ayant accueilli une circulation hydrothermale par le passé. L'étude de ces roches au site ODP 1256, montre que leur porosité est associée à la présence de minéraux d'altération hydrothermale du facies amphibolite (T> 500 °C). La seconde approche a consisté à recréer, en laboratoire, les conditions des systèmes hydrothermaux, à très haute température, afin de prédire les propriétés mécaniques et électriques des basaltes dans ces conditions. Les résultats mécaniques indiquent que la transition fragile/ductile, souvent associée à une forte décroissance de perméabilité, intervient à une température d'environ 550 °C. La mise en place d'une cellule de mesure de la conductivité électrique de haute température a fourni les premiers résultats utiles à l'analyse des données géophysiques. Appliqués aux conditions de la croûte basaltique Islandaise, ces résultats indiquent que des fluides hydrothermaux pourraient circuler au moins transitoirement à l'état supercritique jusqu'à ~ 5 km de profondeur.
https://tel.archives-ouvertes.fr/tel-00591798

tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798/document
https://tel.archives-ouvertes.fr/tel-00591798/file/THESE_MV_pro.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This special issue in honour of the late Olivier Jaoul brings together contributions from experimental and theoretical mineralogy, the area of most of Olivier's own work, focused for the most part on the Earth's mantle. The volume is divided into three sections; diffusion, deformation and seismic properties. New technological developments have often had a strong impact on research in this area, as again shown by Olivier's constant search to improve the resolution of the short diffusion profiles typical of major cations in mantle silicates. In the section on diffusion the impact of improved computer performance for modelling diffusion and point defect configurations on one hand, and high pressure experimental techniques on the other hand, highlight the continued development in this area. The section on deformation deals with wide range of subjects, including the deformation of olivine and quartz and the relation between deformation and diffusion, both subjects close to Olivier's personal interests. This illustrates the new possibilities to undertake deformation experiments at mantle pressures and temperatures, as well as improvement in high-fidelity viscoelastic measurements at high temperature. In the last section on seismic properties we discover theoretical developments on predicting properties near the Earth's surface and a new experimental application, which allows the determination of sound velocity at very high pressures with implications for the Earth's inner core.
ISSN: 0031-9201

hal-00475657
https://hal.archives-ouvertes.fr/hal-00475657
DOI : 10.1016/j.pepi.2008.09.009

Éditeur(s) : Paris : chez l'auteur
Résumé : 2 édition
Siècle(s) traité(s) : 18
Droits : Domaine public
Provenance : Collectivité territoriale de Guyane. Bibliothèque Alexandre-Franconie
Permalien : http://www.manioc.org/patrimon/FRA12337
FRA12337

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : The diamond anvil cell (DAC) is a fundamental device used to explore the properties of materials under extreme pressure and temperature (P/T) conditions. In the past years, simultaneous high P/T DAC experiments using the resistively heated DAC (RH-DAC) techniques have been developed for studying materials properties in a wide P/T range. However, the mechanical instability of metallic gaskets used for sample confinement at high P/T conditions remains a limiting factor for exploiting the accessible P/T range of the RH-DAC. In this study, we present a new gasket configuration that overcomes these limitations. It is based on an amorphous boron-epoxy mixture inserted in a rhenium gasket. We show how these gasket inserts stabilize the sample chamber over a wide P/T range, allowing monitoring sample properties using X-ray diffraction and absorption spectroscopy up to 50GPa and 1620K.
ISSN: 0895-7959

hal-01608425
https://hal.archives-ouvertes.fr/hal-01608425
DOI : 10.1080/08957959.2016.1245297
PRODINRA : 387347

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Here we show that copper substitution in perovskite-type barium strontium cobalt copper oxide (BSCC) membranes confers extremely high oxygen fluxes well beyond the state of art, reaching 27.5 ml cm−2 min−1at 950 °C. A key feature of BSCC is the formation of a mixed matrix catalyst-perovskite membrane caused by the segregation of copper, leading to the formation of an intergranular network of copper-rich oxide between perovskite grains. BSCC membranes delivered pressure normalised oxygen flux (i.e. permeance) of up to 86 times higher, above pressure difference of 18 kPa, as compared to best perovskite membrane, BBSC, due to the catalytic effect of segregated copper oxide. Unlike conventional dual-phase membranes which contain ion and electron conducting phases, this work shows for the first time perovskite-type membranes consisting of a mixed matrix of oxygen ion/electron conducting (perovskite) and catalytic (copper oxide) phases, thus paving the way to the development of high performance membranes for oxygen separation from air for clean energy applications. © 2016 Elsevier B.V.
ISSN: 0376-7388

hal-01683219
https://hal.univ-antilles.fr/hal-01683219
DOI : 10.1016/j.memsci.2016.12.035

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
The age of Ultra-high pressure metamorphism and early cooling remains controversial in the Alps. In a new approach to the problem, samples from the undeformed Hercynian metagranite, Brossasco, were studied using an ultra-violet laser ablation microprobe technique for 40Ar-39Ar dating. The results demonstrate the frequent occurence of excess argon with high 40Ar/36Ar ratios (1000-10000) and a strong relationship between apparent ages and metamorphic textures. The highest excess argon ratios are always associated with high closure temperature minerals or large diffusion domains within single mineral phases. The best interpretation of this relationship seems to be that excess argon was incorporated in all phases during the high pressure event, then mixed with an atmospheric component during rapid cooling and retrogression, producing a wide range of argon concentrations and 40Ar/36Ar ratios. In the present case, some ages in the range 60-110 Ma could be explained by the presence of excess argon incorporated around 40-50 Ma ago. Similar results found in other high-pressure terrains in the Alps may reconcile the argon geochronometer with other systems such as Rb/Sr, U/Pb or Sm/Nd. This study therefore calls for an increasing use of high resolution in-situ sampling techniques to clarify the meaning of 40Ar/39Ar ages in many high pressure terrains.
ISSN: 0010-7999

hal-00197563
https://hal.archives-ouvertes.fr/hal-00197563
https://hal.archives-ouvertes.fr/hal-00197563/document
https://hal.archives-ouvertes.fr/hal-00197563/file/Excess_UV_Arnaud_and_Kelley_GCA_Pub_preprint.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Large sand intrusions often exhibit conical morphologies analogous to magmatic intrusions such as saucer-shaped or cup-shaped sills. Whereas some physical processes may be similar, we show with scaled experiments that the formation of conical sand intrusions may be favoured by the pore-pressure gradients prevailing in the host rock before sand injection. Our experiments involve injecting air into a permeable and cohesive analogue material to produce hydraulic fractures while controlling the pore pressure field. We control the state of overpressure in the overburden by applying homogeneous basal pore pressure, and then adding a second local pore pressure field by injecting air via a central injector to initiate hydraulic fractures near the injection point. In experiments involving small vertical effective stresses (small overburden, or high pore fluid overpressure), the fracturing pressure (lambda(fract)) is supralithostatic and two dipping fractures are initiated at the injection point forming a conical structure. From theoretical considerations, we predict that high values of lambda(fract), are due to strong cohesion or high pore fluid overpressure distributed in the overburden. Such conditions are favoured by the pore pressure/stress coupling induced by both pore pressure fields. The dips of cones can be accounted for elastic-stress rotation occurring around the source. Contrary to magmatic chamber models, the aqueous fluid overpressure developed in a parent sandbody (and prevailing before the formation of injectites) may diffuse into the surrounding overburden, thus favouring stress rotation and the formation of inclined sheets far from the parent source. For experiments involving higher vertical effective stresses (thick overburden or low pore fluid overpressure), the fracturing pressure is lower than the lithostatic stress, and a single fracture is opened in mode I which then grows vertically. At a critical depth, the fracture separates into two dilatant branches forming a flat cone. We make use of a P.I.V. (Particle Imaging Velocimetiy) technique to analyse plastic deformation, showing that these inclined fractures are opened in mixed modes. Close to the surface, they change into steep shear bands where fluids can infiltrate. The final morphology of the fracture network is very similar to the common tripartite architecture of various injection complexes, indicating that different mechanisms may be involved in the formation of dykes. Feeder dykes under the sill zones may open as tensile fractures, while overlying dykes may be guided by the deformation induced by the growth of sills. These deformation conditions may also favour the formation of fluid escape structures and pockmarks. (C) 2011 Elsevier B.V. All rights reserved.
ISSN: 0012-821X

hal-00745640
https://hal.archives-ouvertes.fr/hal-00745640
DOI : 10.1016/j.epsl.2011.10.029

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Convergent plate margins typically experience a transition from subduction to collision dynamics as massive continental blocks enter the subduction channel. Studies of high-pressure rocks indicate that tectonic fragments are rapidly exhumed from eclogite facies to mid-crustal levels, but the details of such dynamics are controversial. To understand the dynamics of a subduction channel we report the results of a petrochronological study from the central Sesia Zone, a key element of the internal Western Alps. This comprises two polymetamorphic basement complexes (Eclogitic Micaschist Complex and Gneiss Minuti Complex) and a thin, dismembered cover sequence (Scalaro Unit) associated with pre-Alpine metagabbros and metasediments (Bonze Unit). Structurally controlled samples from three of these units (Eclogitic Micaschist Complex and Scalaro-Bonze Units) yield unequivocal petrological and geochronological evidence of two distinct high-pressure stages. Ages (U-Th-Pb) of growth zones in accessory allanite and zircon, combined with inclusion and textural relationships, can be tied to the multi-stage evolution of single samples. Two independent tectono-metamorphic 'slices' showing a coherent metamorphic evolution during a given time interval have been recognized: the Fondo slice (which includes Scalaro and Bonze rocks) and the Druer slice (belonging to the Eclogitic Micaschist Complex). The new data indicate separate stages of deformation at eclogite-facies conditions for each recognized independent kilometer-sized tectono-metamorphic slice, between ∼85 and 60 Ma, with evidence of intermittent decompression (ΔP ∼ 0*5 GPa) within only the Fondo slice. The evolution path of the Druer slice indicates a different P-T-time evolution with prolonged eclogite-facies metamorphism between ∼85 and 75 Ma. Our approach, combining structural, petrological and geochronological techniques, yields field-based constraints on the duration and rates of dynamics within a subduction channel.
ISSN: 0022-3530

hal-01054335
https://hal.archives-ouvertes.fr/hal-01054335
DOI : 10.1093/petrology/egu029

Éditeur(s) : HAL CCSD INRA Editions
Résumé : International audience
The objective of this study was to examine the water relations and hydraulic architecture and vulnerability to cavitation in Virola surinamensis and V. michelii and to compare to similar measurements in Eperua falcata. In several previous reports Virola was seen to have a rather narrow range of xylem pressure potentials (Ψx) near zero in the course of a wet-season day while having water fluxes quite close to Eperua. We tested the hypothesis that the narrow range of Ψx might be consistent with very high hydraulic conductivities of stems, roots and shoots and high vulnerability to cavitation in Virola compared to Eperua. When this hypothesis proved false we concluded that the previous determinations of Ψx might be wrong in Virola due to latex. We re-examined the determination of Ψx in Virola by the pressure chamber technique and compared results to determination of Ψleaf by the thermocouple psychrometer technique and found that the likely range of Ψx are more negative than previously reported. Problems concerning the determination of Ψx in species with latex are discussed.
ISSN: 2268-4565

hal-01077475
https://hal.archives-ouvertes.fr/hal-01077475
https://hal.archives-ouvertes.fr/hal-01077475/document
https://hal.archives-ouvertes.fr/hal-01077475/file/JPH-1-e0002.pdf

Résumé : Marine capture fisheries in Jamaica is primarily artisanal in nature ansd is conducted maiinly by fishermen operating from canoes. Approximately 95% of these fishermen operate on the coastal shelf and its associated banks. The commercial species harvested comprise bottom-dwelling, coral reef species and free swimming species of finfish. Other fishery resources of commercial value include marine shrimp, conch and lobsters. Catch statistics are not available for all species, but the Department of Fisheries reports a slight decline in fishery production with production decreasing from 16 milion lbs in 1990, despite the fact that fishing efforts have doubled. Over this period the number of registered fishermen has grown from 12 000 to 16 000, al of whom are engaged in full-time fishing. There arealso part-time fishermen who are not registered. The decline in fish catch is accompanied by a decrease in fish size and quality, suggesting that the fisheries are under pressure and have already exceeded optimum production in relation to vailable resources. As a result the economic returns to fishermen are declining. There are also other problems, such as high incidence of conflicts among fishermen at sea, the high cost of purchasing boats, outboard engine fuel, and equipment, with together with the dangers involved in fishing offshore (piracy, and praedial larceny) create serious social ans economic difficulties for fishermen. Notwithstanding, there is an apparent move on the part of the fishermen to leave the industryor to seek alternative forms of employment. In fact, the Department ofFisheries reports that it is still reciving applications for new licences to operate fishing boats. This is probably due to the fact that where the basis of a community is fishing, it becomes difficult to introduce alternative forms of employment, such as cottage industries, village crafts and other trades. In 1987 the Jamaica Department of Fisheries prepared a Management plan which proposed several conservation measures to promote the efficient use of fisheries resources and to control the development of the Fishery in such a way that the country would receive highest benefits. Adequate attention was given to limitations on fishing gear, institution of closed seasons and related legislation. Strategies to diversify the marine fishing were also proposed. The 1990 five year Devlopment Plan for marine fisheries also focuses on proper resource management in order to reverse trends associated with the overexploitation of marine resources. According to the plan, emphasis will be placed on inland fisheries and mariculture in order to reduce pressure on the fisheries. Inland fisheries in the form of freshwater fish fanning has expanded significantly over the past 10 years with production increasing from less than 0,5 million lbs. in 1980 to in excess of 6.0 million lbs. in 1989. However, some freshwater fish farmers are already experiencing serious competition for water usage and, to a lesser extent for land from crop-producing farmers. The Ministry of Agriculture is of the view that marine cage culture technologically has the potential for introduction in Jamaica . This technologyhas been successfully developed in Norway and the technology is currentlty being experimentally utilized in several countries in the area. The technology, if widely utilized in Jamaica, couls significantly reduce pressure on fisheries, making fishing more cost effective and improve the economic returns to fishermen. Already there exist some technical and institutional capabilities in Jamaica to support commercial development of marine cage culture. The Department of Fisheries has highly trained personnel in aquaculture and marine fisherie, some of whom are directly responsible for the success of freshwater fish fanning. In adition, the Marine Laboratory at the Univesity of the West Indies (UWI) is caarying research on hatchery facilities for marine cage farming. The Department of Fisheries will seek the collaboration ofg the marine unit at UWI which could provide fingerlings of selected marine species for cage 1
Les pêcheries de captage marin en Jamaïque sont principalement de nature artisanale et elles sont dirigées principalement par les pêcheurs qui travaillent depuis des canoës. Environ 95 % de ces pêcheurs travaillent sur la plaine côtière et ses bancs associés. Les espèces commerciales récoltées comprennent les espèces benthiques, les espèces de corail et les espèces de poisson marin de nage libre. D'autres ressources de pêcheries de valeur commerciale comprennent la crevette, la conque et le homard. Les statistiques des pêches ne sont pas disponibles pour toutes les espèces, mais le Département des Pêcheries fait état d'une légère réduction de production de pêcheries, la production se réduisant de 16 millions de livres en 1990, en dépit du fait que les efforts de la pêche ont doublé. Sur cette période le nombre de pêcheurs inscrits a augmenté de 12 000 à 16 000, dont tous sont occupés à plein temps à la pêche. Il y a aussi des pêcheurs à mi-temps qui ne sont pas inscrits. La réduction des pêches est accompagnée d'une réduction de la taille et la qualité des poissons, ce qui implique que les pêcheries sont sous pression et qu'elles ont déjà dépassé la production optimum par rapport aux ressources disponibles. En conséquence, les rendements pour les pêcheurs sont en baisse. Il y a aussi d'autres problèmes, tels qu'un taux élevé de conflits entre les pêcheurs en mer, le coût élevé pour acheter les bateaux, le combustible pour les moteurs hors-bord, et le matériel, ainsi que les dangers impliqués dans la pêche offshore (le piratage, et le vol prédial) ont créé de graves problèmes sociaux et économiques pour les pêcheurs. Néanmoins, il y a une tendance évidente chez les pêcheurs de quitter l'industrie ou de chercher du travail dans d'autres domaines. En fait, le Département des Pêcheries signale qu'il continue de recevoir des demandes de nouveaux permis pour opérer les bateaux de pêche. Ceci est probablement attribuable au fait que là où la base d'une communauté est la pêche, il est difficile d'y introduire des formes alternatives de travail, telles que l'industrie artisanale, l'artisanat de village ou d'autres métiers. Le Département des Pêcheries de la Jamaïque a préparé en 1987 un Projet de gestion qui proposait plusieurs mesures de conservation afin d'encourager l'utilisation efficace des ressources des pêcheries et de contrôler le développement de la Pêcherie de manière que le pays touche le plus de bénéfices. Une attention adéquate a été prêtée aux limitations sur les engins de la pêche, l'établissement de saisons de clôture et les législations associées. Des stratégies pour diversifier la pêche marine ont aussi été proposées. Le Plan de développement quinquennal de 1990 pour les pêcheries marines met l'accent aussi sur la gestion de ressources appropriée afin de faire reculer les tendances associées à la surexploitation des ressources marines. Selon le plan, l'accent sera mis sur les pêcheries intérieures et la mariculture afin de réduire la pression sur les pêcheries. Les pêcheries intérieures, sous la forme de l'élevage de poissons en eau douce, ont pris leur essor sur les 10 dernières années avec une production qui s'est élevée de moins de 0,5 millions de livres en 1980 pour atteindre en 1989 plus de 6.0 millions de livres. Cependant, certains pisciculteurs en eau douce expérimentent déjà une concurrence sérieuse avec les agriculteurs pour l'usage de l'eau et, dans une moindre mesure, de la terre. Le Ministère de l'Agriculture est de l'avis que l'élevage en cage marine a technologiquement le potentiel d'être introduit en Jamaïque. La technologie a été développée avec réussite en Norvège et plusieurs pays dans la région utilisent actuellement la technologie expérimentalement. La technologie, si elle était utilisée en Jamaïque, pourrait réduire de façon significative la pression sur les pêcheries, ce qui rendrait la pêche plus économique et améliorerait les rendements aux pêcheurs. Certaines capacités techniques et institutionnelles existent déjà en Jamaïque qui pourraient soutenir le développement de l'élevage en cage marine. Le Département des Pêcheries a un personnel bien formé en aquaculture et pêcherie marine, dont certains qui sont directement responsables du succès de la pisciculture en eau douce. Par ailleurs, le Laboratoire Marin à l'Université des Antilles (UWI) mène des recherches sur les installations d'écloseries pour l'élevage en cage marine. Le Département des Pêcheries demandera la collaboration de l'unité marine à l'UWI qui pourra fournir des saumoneaux d'espèces marines sélectionnées pour la cage 1.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/1993/rapport-1918.pdf
http://archimer.ifremer.fr/doc/00000/1918/

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
We predict the IR-TO, IR-LO and Raman modes (wave numbers and intensities) of magnesite (MgCO3) up to 50 GPa, at T = 0 K, using the density-functional perturbation theory up to a third order perturbation, under the harmonic assumption. The predicted IR-TO and Raman mode wave numbers, the mode Grüneisen parameters and the Davydov splittings are systematically compared with experimental data for all modes up to the pressures of 10-30 GPa and for some modes up to 50 GPa. Existing experiments allow extending this comparison only to IR-LO wave numbers of the E u (ν3) asymmetric-stretch mode, confirming the odd experimental behavior of this mode at very high pressures. Predicted IR-TO, IR-LO and Raman intensities up to 50 GPa are just tabulated, but data are missing for their comparison with precise experiments. However, the generally good agreement observed between numerical results and experimental data, when their comparison is possible, suggests that first-principles methods are a major help to predict the entire spectrum up to very high pressures.
ISSN: 0342-1791

hal-00527834
https://hal.archives-ouvertes.fr/hal-00527834
DOI : 10.1007/s00269-010-0395-y

Éditeur(s) : HAL CCSD Elsevier
Résumé : Nominally anhydrous minerals (NAMs) of Earth's mantle can contain hydrogen as atomic impurity in their crystal structures. This hydrogen substantially modifies many physical properties of Earth's mantle rocks. Also, the Earth's deep interior is made of rocks where minerals are separated by nanometer-scale interfaces call grain boundaries and interphase boundaries. These grain boundaries should carefully be considered as a potential hydrogen reservoir as well. I report here an experimental investigation of hydrogen diffusion through grain boundaries in olivine polycrystalline aggregates. Hot-press and diffusion experiments were performed using a gas-medium high-pressure vessel at a confining pressure of 300 MPa, over a temperature range of 1000-1200 degrees C. The diffusion assembly consisted of a dense polycrystalline cylinder of natural olivine from San Carlos (Arizona) mixed with olivine singles crystals of millimeter size. This mixture was couple with a talc cylinder. Ni capsule were used to buffer the oxygen fugacity at Ni-NiO level. Experiment durations varied from 3 min to 4 h. The presence of hydrogen in the sample was quantified using Fourier transform infrared spectroscopy. The calculation of the diffusion coefficients was based on the estimation of the length of polycrystalline solid affected by the diffusion of hydrogen. The absence or presence of hydrogen was recorded by the large olivines behaving here as "hydrogen sensor", which are implanted in the aggregate. The results indicate that effective hydrogen diffusivity which includes grain boundaries effect in olivine aggregate is barely one order of magnitude faster than hydrogen diffusion in an olivine single crystal with a diffusivity similar to 8.5x 10(-10) m(2) s(-1) 1000 degrees C and only twice faster similar to 2.1 x10(-9) m(2) s(-1) 1200 degrees C. Calculations of the diffusion data in relation to the Arrhenius Law, yield an activation energy of similar to 70 +/- 10 kJ mol(-l) . From these effective diffusivities and combined with published diffusion data for olivine single crystals, hydrogen diffusion in grain boundaries is extracted and yield diffusivities almost three order of magnitude faster (similar to 5 x 10(-6) m(2) s(-1) at 1200 degrees C) than in an olivine single crystal at the equivalent high temperature. On geological scales and for coarse-grain rocks, hydrogen diffusivity in grain boundaries is not fast enough to compete with lattice diffusion. The relative large grain size of mantle rocks will ensure a very limited hydrogen transport by effective diffusion, and a good conservation of water-rich zones in the Earth's mantle.
ISSN: 0012-821X

hal-00512821
https://hal.archives-ouvertes.fr/hal-00512821
DOI : 10.1016/j.epsl.2010.04.019

Éditeur(s) : HAL CCSD
Résumé : HYDRO
The objective of this study was to examine the water relations and hydraulic architecture and vulnerability to cavitation in Virola surinamensis and V. michelii and to compare to similar measurements in Eperua falcata. In several previous reports Virola was seen to have a rather narrow range of xylem pressure potentials ( Yx) near zero in the course of a wet-season day while having water fluxes quite close to Eperua. We tested the hypothesis that the narrow range of Yx might be consistent with very high hydraulic conductivities of stems, roots and shoots and high vulnerability to cavitation in Virola compared to Eperua. When this hypothesis proved false we concluded that the previous determinations of Y x might be wrong in Virola due to latex. We re-examined the determination of Yx in Virola by the pressure chamber technique and compared results to determination of Yleaf by the thermocouple psychrometer technique and found that the likely range of Yx are more negative than previously reported. Problems concerning the determination of Yx in species with latex are discussed.
Journal of Sigmoidal Plant Hydraulics

hal-01032396
https://hal.archives-ouvertes.fr/hal-01032396

Éditeur(s) : Elsevier
Résumé : In the Caribbean, snappers (Lutjanidae) and groupers (Serranidae) are often heavily exploited by artisanal or industrial fisheries. This paper analyzes the catches of an artisanal fishery selectively targeting these species with a moderate fishing pressure in the Bay Islands (Honduras), and discusses the implications on the understanding of the early stages of development of reef fisheries. Although snappers and groupers are targeted with handlines and spearguns in the whole archipelago, the differences in species diversity and size structure of the catch reveals various exploitation patterns. In most areas, a depletion is observed for the most vulnerable snapper and grouper species, and most other species are mainly exploited in their juvenile phase; clear signs of an intensification process are apparent in one of the areas. The comparison of the relative production in the Bay Islands with other reef fisheries in the Caribbean suggests that higher values may be related to moderate fishing pressure and appropriate combinations of fishing effort and selectivity. This example shows how fisheries strictly targeting a high quality resource with selective fishing techniques can be quite productive even at high levels of effort, but also that they are progressively lead to broaden their species range (sooner or later at the expense of the most vulnerable, often large-sized, species) while increasingly using less selective gears.
Fisheries Research (0165-7836) (Elsevier), 2005-06 , Vol. 73 , N. 1-2 , P. 159-169

Droits : 2004 Elsevier B.V. All rights reserved
http://archimer.ifremer.fr/doc/2005/publication-512.pdf
DOI:10.1016/j.fishres.2004.12.008
http://archimer.ifremer.fr/doc/00000/512/

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
A San Carlos olivine polycrystal has been deformed under uppermost mantle conditions, by compression at 900 °C, at a strain rate of 1.1 × 10−5 s−1, under a confining pressure of 300 MPa, using the Paterson press. Transmission electron tomography of dislocations has been performed by scanning transmission electron microscopy, by conventional transmission electron microscopy using the weak-beam dark-field technique, associated with precession or not, in order to determine the glide planes of [001] screw dislocations. This recent technique is the most suitable one since most [001] dislocations exhibit straight screw segments due to the high lattice friction on this character at low temperature. We find that [001] dislocations glide in (100), (010) and {110} as already reported, but also more unexpectedly in {120} and {130}. We show that at 900 °C, [001] {110} glide is dominant in polycrystals. We have, however, noted and characterized numerous cross-slip events in the specimen.
ISSN: 0342-1791

hal-01054330
https://hal.archives-ouvertes.fr/hal-01054330
DOI : 10.1007/s00269-014-0665-1

Éditeur(s) : HAL CCSD
Résumé : Water vapour is highly variable in the atmosphere with concentration reaching saturation in the tropics and with dry areas over elevated continental region. Good knowledge of the amount of integrated water vapour in the air is necessary to predict phase changes and in particular precipitation. Water vapour variability measurements are still insufficient with standard observing systems. Moreover accurate GPS antenna positioning is affected by the refractivity index variation in the troposphere. Consequently, vertical positioning component estimation is difficult. This variation is directly linked to distribution of variables such as pressure, temperature and humidity along the path between satellite and receiver. Here we study more specifically heavy rains et notably Cevenols events. This thesis work consists to check the GPS measurement validity to quantify water vapour in comparison with measurements from radiosoundings and meteorological model outputs. GPS observations and flux surface information have been analysed to see if water vapour quantification by GPS allowed characterising heavy rain events (cumulative rainfall amount greater than 150 mm). Then, we tested the GPS data assimilation impact on cumulative precipitation forecasts using the high resolution Meteo France AROME model (2.5 km). Finally the quality and the contribution of GPS measurement on sea is evaluated for water vapour measurement. This study has been realised in the framework of VAPIMED experiment.
La vapeur d'eau varie largement dans l'atmosphère avec des concentrations allant de la saturation dans les tropiques à des zones presque sèches au-dessus des zones continentales élevées. Une bonne connaissance du contenu en vapeur d'eau dans l'air est nécessaire pour la prévision des changements de phases, notamment les précipitations. La mesure de la variabilité de la vapeur d'eau est une lacune des systèmes d'observation. Par ailleurs, il est apparu que le positionnement précis des antennes GPS était affecté par la variation de l'indice de réfraction dans la troposphère, ce qui rend particulièrement difficile l'estimation de la composante verticale. Cette variation est directement liée à la distribution des variables pression, température et humidité sur les trajets satellite-récepteur. On s'intéresse ici à l'étude des précipitations intenses et notamment aux épisodes Cévenols. Ce travail de thèse consiste à vérifier la validité de la mesure GPS pour la quantification de la vapeur d'eau en la comparant avec des mesures issues de radiosondage et des sorties de modèle météorologique. On cherche à analyser si la quantification de vapeur d'eau par GPS permet de caractériser les forts événements précipitants (cumuls supérieurs à 150 mm) à l'aide d'observations conjointes sur les flux de surface. On étudie ensuite l'impact de l'assimilation de données GPS issues d'un réseau GPS dense sur la prévision des cumuls de pluies dans le modèle à hauterésolution (2.5 km) AROME de Météo France. Finalement on évalue la qualité et l'apport de la mesure de vapeur d'eau par GPS en mer dans le cadre d'une campagne de mesure VAPIMED).
https://tel.archives-ouvertes.fr/tel-00444081

Droits : info:eu-repo/semantics/OpenAccess
tel-00444081
https://tel.archives-ouvertes.fr/tel-00444081
https://tel.archives-ouvertes.fr/tel-00444081/document
https://tel.archives-ouvertes.fr/tel-00444081/file/These_KBoniface.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Alpine Corsica consists of a stack of variably metamorphosed units of continental and Tethys-derived rocks. It represents an excellent example of high-pressure (HP) orogenic belt, such as the Western Alps, exposed over a small and accessible area. Compared to the Western Alps, the geology of Alpine Corsica is poorly unraveled. During the 1970s-80s, based on either lithostratigraphic or metamorphic field observations, various classifications of the belt have been proposed, but these classifications have been rarely matched together. Furthermore, through time, the internal complexity of large domains has been progressively left aside in the frame of large-scale geodynamic reconstructions. As a consequence, major open questions on the internal structure of the belt have remained unsolved. Apart from a few local studies, Alpine Corsica has not benefited of modern developments in petrology and basin research. This feature results in several uncertainties when combining lithostratigraphic and metamorphic patterns and, consequently, in the definition of an exhaustive architecture of the belt. In this paper we provide a review on the geology of Alpine Corsica, paying particular attention to the available lithostratigraphic and metamorphic classifications of the metamorphic terranes. These data are completed by a new and exhaustive metamorphic dataset obtained by means of thermometry based on Raman Spectroscopy of Carbonaceous Material (RSCM). This technique provides reliable insights on the peak temperature of the metamorphic history for CM-bearing metasediments. A detailed metamorphic characterization of metasediments, which have been previously largely ignored due to retrogression or to the lack of diagnostic mineralogy, is thus obtained and fruitfully coupled with the available lithostratigraphic data. Nine main tectono-metamorphic units are defined, from subgreenschist (ca. 280-300 °C) to the lawsonite-eclogite-facies (ca. 500-550 °C) condition. These units are homogeneous in metamorphism, laterally continuous and have characteristic lithostratigraphic features. This study also suggests a direct link between the pre-orogenic extensional setting and the present-day compressional structure of Alpine Corsica, indicating that large sections of subducted lithosphere were subducted and exhumed as coherent domains. These features provide important insight on the mechanism of stacking and exhumation of HP rocks, and make Alpine Corsica a unique reference for mountain-building processes in Tethyan-type orogens.
ISSN: 0012-8252

hal-00814433
https://hal.archives-ouvertes.fr/hal-00814433
DOI : 10.1016/j.earscirev.2012.10.003

Éditeur(s) : HAL CCSD
Résumé : International audience
Seismic anisotropy is a ubiquitous feature of the subcontinental mantle. This can be inferred both from direct seismic observations of shear wave splitting from teleseismic shear waves, as well as the petrofabric analyses of mantle nodules from kimberlite pipes. The anisotropy is principally due to the strain-induced lattice preferred orientation (LPO) of olivine. The combined use of these mantle samples, deformation experiments on olivine, and numerical modeling of LPO, provides a critical framework for making inferences about mantle deformation from observed seismic anisotropy. In most cases there is a close correspondence between mantle deformation derived from seismic observations of anisotropy, and crustal deformation, from the Archean to the present. This implies that the mantle plays a major, if not dominant role in continental deformation. No clear evidence is found for a continental asthenospheric decoupling zone, suggesting that continents are probably coupled to general mantle circulation.
Mantle Petrology: Field Observations and high Pressure experimentations: a Tribute to Francis R. (Joe) Boyd

hal-01391514
http://hal.univ-reunion.fr/hal-01391514
http://hal.univ-reunion.fr/hal-01391514/document
http://hal.univ-reunion.fr/hal-01391514/file/Silver_et_al_BoydVolume 1999_hal.pdf

Éditeur(s) : Pêche thonière et dispositifs de concentration de poissons, Caribbean-Martinique, 15-19 Oct 1999
Résumé : In early 1980s, fad fisheries were introduced from the Philippines to Japan, mainly to Okinawa. The fisheries have well developed becoming one of the main fisheries in Okinawa where 210 fads are approved to deploy in 1999. The annual catch by roughly 1 000 boats (most of them are small) is 2500-4000 mt; average catch from one fad is about 20 mt; average catch by one boat on one day is 73 kilogrammes. fads are also important for easing the fishing pressures on bottom fish stocks. Most of the fads were deployed and managed by local fishermen's groups that have improved the structures of the system to withstand typhoons. The catches are strongly depending on the sites, usually the farther offshore, the better the catches. A variety of fishing methods are devised targeting each species and the size of the fish. Being most abundant and having relatively higher prices, yellowfin tuna is the most important and consists 68% of the total production. There have been conflicts among fishermen on the use of fads since the early stage of the fisheries development. Now, the number of fads is regulated by a management committee. Conflicts between fishermen and sport fishermen have become problems; on the other hand, the sport fishing could lead to further development of the fisheries. Degraded fish meat caused by high meat temperature and occasional oversupply have been major marketing problems since prices are strongly related to the meat quality and the fish supply.

Droits : Ifremer
http://archimer.ifremer.fr/doc/00042/15281/12667.pdf
http://archimer.ifremer.fr/doc/00042/15281/